Structural, morphological, and optical properties of carbon nanoparticles unsheathed from date palm fronds.

Several studies have reported the synthesis of carbon nanoparticles (CNPs) by various methods. In this study, an easy one-step process to unsheathe CNPs from date palm fronds through a top-down ball milling method has been reported. The CNPs were characterized using various spectroscopic and microscopic methods to determine their structural and morphological features, optical properties, crystallinity, physicochemical properties, and particle stability. Transmission electron microscopy (TEM) revealed that the obtained CNPs' size ranged from 4 to 22 nm in a crystalline form. Scanning electron microscopy (SEM) confirmed their spherical shape, while the maximum photoluminescence (PL) intensity was recorded at 464 nm when excited at 375 nm. The unsheathed CNPs produced a good quantum yield (QY) of 3.24%. Furthermore, the CNPs exhibited high Raman ratios of I D/I G and I 2D/I G with values of 0.59 and 0.04, respectively, verifying their multilayer crystalline graphitic nature. These Raman ratios also agree with the X-ray diffractometry (XRD) results. The CNPs' sp2 and sp3 carbon bonds were confirmed by X-ray photoelectron spectroscopy (XPS), with oxygen on the surface forming carboxyl and carbonyl groups with no other observable impurities. Furthermore, the extracted CNPs showed excellent PL properties for up- and down-conversion. These properties are exemplary for low-cost biomass with potential applications in biomedicine. Therefore, the extracted CNPs reported in this study have potential applications in optical imaging.

Evaluation of some pollutant levels in environmental samples collected from the area of the new campus of Taif University.

The levels of radioactivity and heavy metals in soil, plant and groundwater samples collected from the area of the new campus of Taif University, Saudi Arabia, and its neighbouring areas have been determined. High-resolution gamma-ray spectroscopy was used for radioactivity measurements, and inductively coupled plasma atomic emission spectroscopy was used to determine the concentration of heavy metals. The means of (226)Ra, (228)Ra and (40)K concentrations in water samples collected from four wells were found to be 0.13 ± 0.03, 0.05 ± 0.03 and 1.3 ± 0.5 Bq l(-1), respectively. The means of (238)U, (226)Ra, (228)Ra ((232)Th for soil samples) and (40)K concentrations in wild plant and soil samples were found to be 3.7 ± 4.1, 8.8 ± 11.6, 3.8 ± 2.9 and 1025 ± 685, and 8.6 ± 3.4, 12.8 ± 3.4, 16.6 ± 7.1 and 618 ± 82 Bq kg(-1) dry weight (DW), respectively. The (137)Cs of artificial origin was also detected in soil samples with a mean concentration of 3.8 ± 2.2 Bq kg(-1) DW. Evaluating the results, it can be concluded that the concentrations of (238)U, (226)Ra, (232)Th and (40)K in soil samples fall within the world average. Furthermore, 19 trace and major elements in groundwater samples and 22 elements in soil and plant samples were determined. The sampling locations of soil can be classified into three groups (relatively high, medium and low polluted) according to their calculated metal pollution index using the contents of trace and major elements. A cluster analysis of the contents of radioactivity and trace element contents in soil samples shows the presence of two main distinct clusters of sampling locations.

A preliminary investigation of the EBT2 radiochromic films response to low energy fast neutrons.

EBT2 radiochromic films were used to study the relative dose distribution of the neutron field. The correlation between the beam current and the optical density showed good linear dependence with a correlation coefficient exceeding 98%. At any given beam energy, neutron dose rates can be changed by a factor of 40 without changing the neutron spectrum. This result is consistent with what was found by the Tissue Equivalent Proportional Counter measurements. The uniformity of the neutron field was inspected by the optical density profile of the exposed film.